Synthesis and characterization of rhodium-aluminum heterobimetallic complexes tethered by a 1,3-bis(diphenylphosphino)-2-propanoxy group.
PMID 31123745 · Dalton transactions (Cambridge, England : 2003) · 2019 · DOI 10.1039/c9dt00938h
Authors: Zhongjing Li; Timothy W Yokley; Sheila L Tran; Jie Zong; Nathan D Schley; Timothy P Brewster
Abstract
We demonstrate the synthesis and characterization of a new class of late transition metal-aluminum heterobimetallic complexes. A bridging ligand which both chelates the transition metal and binds the aluminum via an alkoxide was employed to impart stability to the bimetallic system. Novel rhodium-aluminum heterobimetallic complexes Rh(DPPE)(DPPP-O-AliBu2Cl) and Rh(DPPP-O-AliBu2)(DPPP-O-AliBu2Cl) are synthesized and spectroscopically characterized.
Cite
Zhongjing Li; Timothy W Yokley; Sheila L Tran; Jie Zong; Nathan D Schley; Timothy P Brewster. Synthesis and characterization of rhodium-aluminum heterobimetallic complexes tethered by a 1,3-bis(diphenylphosphino)-2-propanoxy group. Dalton transactions (Cambridge, England : 2003) (2019). PMID 31123745. DOI 10.1039/c9dt00938h.